HA, funny that this comes up. DND Beyond doesn't have a d100, so I opened my ChatGPT sub and had it roll a d100 for me a few times so I could use my magic beans properly.
Yup! Also one has to mind the order in which one rolls the dice. Since 10 and 5 could be either 05 or 50. As a bonus, if you roll them in order of "tens" to "ones", getting 10 on the first dice has added suspense since the latter dice determines if it is going to count as a low roll of 0X (by rolling 1-9 on the next dice X) or if it is going to be a max roll of 100 (by rolling another 10).
Probably just because it's prime. It's just that humans are terrible at understanding the concept of randomness. A study by Theodore P. Hill showed that when tasked to pick a random number between 1 and 10, almost a third of the subjects (n was over 8500) picked 7. 10 was the least picked number (if you ditch the few idiots that picked 0).