What I can glance is that photosynthesis has (probably) evolved independently 6 time in Bacteria and 3 times in Eukaryotes.
Plants evolved to photosynthesise after photosynthesising bacteria already existed for billions of years.
(But then we have to also acknowledge that multicellular life evolved like 25 times in Eukaryotes, and the Eukaryote - aka Mitochondria-"Powerhouse of the cell"-haver- is the real big step as it only happened once to our knowledge).